Improved Enantioselectivity in Asymmetric Dihydroxylation of Terminal Olefins Using Pyrimidine Ligands

DOI: 10.1021/jo00067a002

Source and publish data:

Journal of Organic Chemistry p. 3785 - 3786 (1993)

Update date:2022-08-30

Topics:

Authors:

Crispino, Gerard A.

Jeong, Kyu-Sung

Kolb, Hartmuth C.

Wang, Zhi-Min

Xu, Daqiang

Sharpless, K. Barry

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Article abstract of DOI:10.1021/jo00067a002

Bis-cinchona alkaloid substituted pyrimidine ligands were found to give improved enantioselectivity in the osmium-catalyzed asymmetric dihydroxylation (AD) of monosubstituted terminal olefins.

Full text of DOI:10.1021/jo00067a002

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