Ruthenium-Catalyzed Oxidation of Nonactivated Alcohols by MnO2

DOI: 10.1021/jo00084a044

Source and publish data:

Journal of Organic Chemistry p. 1196 - 1198 (1994)

Update date:2022-08-12

Topics:

Authors:

Karlsson, Ulrika

Wang, Guo-Zhi

Baeckvall, Jan-E.

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Article abstract of DOI:10.1021/jo00084a044

Nonactivated alcohols are oxidized to ketones by MnO2 in the presence of a catalytic system consisting of 2 (1) and 2,6-di-tert-butylbenzoquinone (2).The reaction proceeds via a ruthenium-catalyzed dehydrogenation of the alcohol and subsequent hydrogen transfer to 2,6-di-tert-butylbenzoquinone (2).The hydroquinone formed is reoxidized to quinone by MnO2.

Full text of DOI:10.1021/jo00084a044

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