A MILD GENERAL METHOD FOR THE SYNTHESIS OF α-2-DEOXY-DISACCHARIDES: SYNTHESIS OF L-OLEANDROSYL-L-OLEANDROSE FROM D-GLUCOSE

DOI: 10.1016/S0040-4039(01)80712-7

Source and publish data:

Tetrahedron Letters p. 4287 - 4290 (1989)

Update date:2022-08-16

Topics:

Authors:

Ravi, D.

Kulkarni, Vinayak R.

Mereyala, Hari Babu

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Article abstract of DOI:10.1016/S0040-4039(01)80712-7

A mild, general method for the stereoselective synthesis of α-2-deoxy disaccharides is described using 2-deoxy-2-pyridyl 1-thioglycosides 4, 7, 8 as glycosyl donors and methyl iodide as an activator.Thus, a disaccharide 6 component of avermectin family is synthesized starting from D-glucose.

Full text of DOI:10.1016/S0040-4039(01)80712-7

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