Chemistry Letters p. 391 - 394 (1981)
Update date:2022-08-16
Topics:
Okuhara, Toshio
Kasai, Atsushi
Hayakawa, Nobukiyo
Misono, Makoto
Yoneda, Yukio
Organic compounds containing oxygen and nitrogen like alcohols and pyridine were readily incorporated into the bulk of heteropoly acids, while hydrocarbons such as butenes and benzene were adsorbed only on the surface.It was found in the dehydration of ethanol over H3PW12O40 that ethylene was yielded predominantly from absorbed ethanol in the bulk, whereas diethyl ether was formed on the surface.
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