OUVERTURE ENANTIODIVERGENTE DE L'EPOXYSTYRENE (R) PAR Me3SiN3 CATALYSEE PAR Al(O-iPr)3 ET Ti(O-iPr)4

DOI: 10.1016/S0040-4039(01)80771-1

Source and publish data:

Tetrahedron Letters p. 4673 - 4676 (1989)

Update date:2022-08-03

Topics:

Authors:

Sutowardoyo, K.

Emziane, M.

Sinou, D.

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Article abstract of DOI:10.1016/S0040-4039(01)80771-1

Ring-opening of (R) epoxystyrene with Me3SiN3 in the presence of Al(O-iPr)3 gives only the (S) silylated azidohydrine.Use of Ti(O-iPr)4 leads to the enantiodivergent opening of the epoxide, depending upon the solvent used.

Full text of DOI:10.1016/S0040-4039(01)80771-1

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