Formation of S,S-diphenyl-S-methoxythiazyne Ph2S(OMe)(≡N) in the alkaline hydrolysis of S,S-diphenyl-N-halosulfilimines

Article abstract of DOI:10.1016/S0040-4039(01)93888-2

The structure of a compound formed during the alkaline hydrolysis of S,S-diphenyl-N-halosulfilimines to the corresponding sulfoximine in methanol was assigned to PhS(OMe) (≡N) Ph, S,S-diphenyl-S-methoxythiazyne, on the basis of spectroscopic analyses and chemical reactions.