Journal of Organometallic Chemistry p. C1 - C6 (1990)
Update date:2022-08-17
Topics:
Colomer, Ernest
Corriu, Robert J. P.
Pleixats, Roser
The dimethylsilylcyclopentadienide anion undergoes cleavage of the silicon-cyclopentadienyl bond upon attempted complexation with transition metals.Complexes bearing such ligands can be obtained by metallation of the cyclopentadienyl ligand in tricarbonyl(η5-cyclopentadienyl)manganese, ferrocene and ruthenocene, followed by reaction with chlorodimethylsilane.The silicon-hydrogen function can react with carbonyl cobalt or carbonyl(hydrido)tris(triphenylphosphine)iridium, to give heterobimetallic complexes in which cyclopentadienyldimethylsilane acts as an assembling ligand.Similar complexes are obtained starting from tricarbonyl(η6-benzene)chromium.
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