REACTIONS D'INSERTION DU MONOXYDE DE CARBONE ET DU CYCLOHEXYLISONITRILE DANS LES LIAISONS Ti-ALKYLE ET Ti-ARYLE. PREMIER EXEMPLE DE REACTION D'INSERTION DANS UNE LIAISON METAL DE TRANSITION-LIGAND PERFLUOROARYLE

DOI: 10.1016/S0022-328X(00)90292-4

Source and publish data:

Journal of Organometallic Chemistry p. 321 - 328 (1980)

Update date:2022-08-11

Topics:

Authors:

Dormond, A.

Dahchour, A.

Read Full Text PDF DownLoad Join now for total 90,000,000 free articles

Article abstract of DOI:10.1016/S0022-328X(00)90292-4

Carbon monoxide inserts exclusively into the Ti-CH3 bond of Cp2Ti(C6F5)CH3 while cyclohexyl isocyanide inserts only into the Ti-C6F5 bond, giving Cp2TiCH3.The latter reaction is the first example of insertion into a transition metal-fluorocarbon ligand bond.Starting from Cp2Ti(C6H5)CH3, only Cp2TiCH3 is obtained.

Full text of DOI:10.1016/S0022-328X(00)90292-4

Products guided by the article

Product name:Titanocene dichloride

Cas No:1271-19-8

R&D Labs maybe for 1271-19-8

JiangXi Keyuan Biopharma Co., LTD.

Contact:+86-563-6833666

Address:Guangde Fine Chemical Zone, Anhui Province, China
Sichuan Mianzhu Ronghong Chemical Co.,LTd

Contact:8613981840544

Address:XINSHI INDUSTRY PARK,MIANZHU,SICHUAN,CHINA
BOC Sciences

website:https://www.bocsci.com/

Contact:1-631-485-4226

Address:Ramsey Road
Xi'an Yuri Solar Co., Ltd

website:https://www.yurisolar.com/en

Contact:86--18092602675

Address:No. 560, East Hangtian Road, Xi'an, China
Jiangsu Fengshan Group Co., Ltd.

Contact:86-25-86558671

Address:1903,Central International Mansion 105-6 North Zhongshan Road, Nanjing, China

Relevant to this article

Localization of technetium 99m-ethylenediamine-N, N'-bis(α-2-hydroxy-5-bromophenyl)acetic acid and technetium ggm-N-(2-mercapto-1-oxopropyl)glycine in hepatobiliary system

Doi:10.1002/jps.2600690528
(1980)
Sulfate-promoted titania photocatalyst for high efficiency gas phase toluene degradation

Doi:10.1246/cl.2005.336
(2005)
Catalytic Conversion of N-Heteroaromatics to Functionalized Arylamines by Merging Hydrogen Transfer and Selective Coupling

Doi:10.1021/acscatal.0c00394
(2020)
Programmable Synthesis of 2-Deoxyglycosides

Doi:10.1021/jacs.9b03982
(2020)
Reactions of 2-chlorobutane with polynuclear bimetallic aluminum and cobalt chloride complexes: Low-temperature synthesis and structure of adducts

Doi:10.1007/s11172-010-0214-0
(2010)
Structural characterization of dodecyltrimethylammonium (DTMA) bromide modified sepiolite and its adsorption isotherm studies

Doi:10.1016/j.molstruc.2011.09.044
(2012)

Article Doi