REACTIONS D'INSERTION DU MONOXYDE DE CARBONE ET DU CYCLOHEXYLISONITRILE DANS LES LIAISONS Ti-ALKYLE ET Ti-ARYLE. PREMIER EXEMPLE DE REACTION D'INSERTION DANS UNE LIAISON METAL DE TRANSITION-LIGAND PERFLUOROARYLE

Article abstract of DOI:10.1016/S0022-328X(00)90292-4

Carbon monoxide inserts exclusively into the Ti-CH3 bond of Cp2Ti(C6F5)CH3 while cyclohexyl isocyanide inserts only into the Ti-C6F5 bond, giving Cp2TiCH3.The latter reaction is the first example of insertion into a transition metal-fluorocarbon ligand bond.Starting from Cp2Ti(C6H5)CH3, only Cp2TiCH3 is obtained.