Journal of Organometallic Chemistry p. 113 - 117 (1992)
Update date:2022-08-30
Topics:
Doisneau, G.
Balavoine, G.
Fillebeen-Khan, T.
The conversion of acetylferrocene or diacetylferrocene into ethynylferrocene 1 or diethynylferrocene 4, respectively, is achieved in good yield in a one-pot synthesis using Negishi's reagent.The diethynylferrocene is isolated as its trimethylsilylderivative 5.The complexes 1 and 5 undergo various nucleophilic substitution reactions, resulting in new ferrocenyl derivatives.
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