Electrooxidative Coupling of Phenols. I. Product-Selective Electrosynthesis of 2,2',6,6'-Tetra-tert-butyl-1,1'-biphenol from 2,6-Di-tert-butylphenol

DOI: 10.1016/S0040-4039(01)93724-4

Source and publish data:

Tetrahedron Letters p. 2105 - 2108 (1989)

Update date:2022-08-16

Topics:

Authors:

Torii, Sigeru

Dhimane, Anne-Lise

Araki, Yoshitaka

Inokuchi, Tsutomu

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Article abstract of DOI:10.1016/S0040-4039(01)93724-4

Biphenol electrosynthesis is achieved in a divided cell by a set of redox reactions from 2,6-di-tert-butylphenol (4) via the corresponding diphenoquinone 3.Phenol 4 can also lead to either the corresponding biphenol 2 or diphenoquinone 3 in a product-selective manner by electrooxidation in an undivided cell.The choice of solvent is a crucial factor for the product-selectivity.

Full text of DOI:10.1016/S0040-4039(01)93724-4

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Product name:3,3',5,5'-TETRA(TERT-BUTYL)[1,1'-BIPHENYL]-4,4'-DIOL

Cas No:128-38-1

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