Synthesis of Me2> (tmeda = tetramethylethylenediamine) and of a Binuclear Zirconocene Phosphine Functionalized Ketene Complex, (Both Structurally Characterized), the Latter via Carbonylation of ''

DOI: 10.1039/c39840000220

Source and publish data:

Journal of the Chemical Society. Chemical communications p. 220 - 222 (1984)

Update date:2022-08-11

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Authors:

Engelhardt, Lutz M.

Jacobsen, Geraldine E.

Raston, Colin L.

White, Allan H.

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Article abstract of DOI:10.1039/c39840000220

Reaction of <(tmeda)-cycloMe2>, (1), (tmeda = tetramethylethylenediamine) with <(η-C5H5)2ZrCl2> in tetrahydrofuran at - 78 deg C yields <(η-C5H5)2Zr(CH2PMe2)nCl_2-n>, n = 1, (2), or n = 2, (3); carbonylation of (2) affords exclusively a novel binuclear ketene complex, , (4), which in the crystal form possesses a Zr-P linkage <2.724(5) Angstroem>.

Full text of DOI:10.1039/c39840000220

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