The Effect of Strain on the Catalytic Reactions of Bridged Thiazolium Salts as Models of Thiamin

DOI: 10.1039/c39900000961

Source and publish data:

Journal of the Chemical Society. Chemical communications p. 961 - 963 (1990)

Update date:2022-08-15

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Authors:

Leeper, Finian J.

Smith, David H. C.

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Article abstract of DOI:10.1039/c39900000961

The reactivity of bridged thiazolium salts (9) and (10) has been studied; the model (9) with the shorter bridge is unable to catalyse the benzoin condensation reaction and it was shown that this is due to failure of the condensation step (5) -> (6), proba

Full text of DOI:10.1039/c39900000961

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