Journal of the American Chemical Society p. 9586 - 9590 (1990)
Update date:2022-09-26
Topics:
Tecilla, Paolo
Chang, Suk-Kyu
Hamilton, Andrew D.
An artificial receptor that is complementary to the proposed trigonal-bipyramidal intermediate for phosphoryl-transfer reactions has been designed. Kinetic measurements with 31P NMR methods show that the receptor causes up to a 10-fold acceleration in the aminolysis of phosphorodiamidic chloride derivatives, proceeding via an associative mechanism.
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