Chemistry Letters p. 689 - 692 (1988)
Update date:2022-08-25
Topics:
Komiyama, Makoto
Stereospecific cleavage of adenosine 2',3'-cyclic monophosphate to the 2'-monophosphate is achieved at pH 11.08, 20 deg C by use of β- and γ-cyclodexrins as catalysts.The 2'/3' ratio for the product is 7.7 at the concentration 1.5x10-2 mol dm-3 of β-cyclodextrin.In contrast, α-cyclodextrin promotes the formation of the 3'-monophosphate, giving the product 2'/3' ratio 0.49 at the concentration 1.0x10-2 mol dm-3.
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