Effect of carbenoid structure on the reactivity of rhodium-stabilized carbenoids

DOI: 10.1016/S0040-4039(98)00836-3

Source and publish data:

Tetrahedron Letters p. 4417 - 4420 (1998)

Update date:2022-09-26

Topics:

Authors:

Davies, Huw M. L.

Hodges, L. Mark

Matasi, Julius J.

Hansen, Tore

Stafford, Douglas G.

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Article abstract of DOI:10.1016/S0040-4039(98)00836-3

The outcome of rhodium(II) pivalate catalyzed decomposition of diaozoacetates in the presence of cyclohexane is highly dependent on carbenoid structure. Carbenoids derived from phenyldiazoacetates or diazoketoesters undergo high yielding intermolecular C-H insertions while other carbenoid systems undergo rearrangements, dimerization or trimerization.

Full text of DOI:10.1016/S0040-4039(98)00836-3

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