Preparation and rearrangement of 2-allyloxyethyl aryl sulfoxides; a mercury-free claisen sequence

DOI: 10.1016/S0040-4039(00)94494-0

Source and publish data:

Tetrahedron Letters p. 4041 - 4044 (1990)

Update date:2022-09-26

Topics:

Authors:

Mandai, Tadakatsu

Ueda, Masaki

Hasegawa, Shun-Ichi

Kawada, Mikio

Tsuji, Jiro

Saito, Seiki

Read Full Text PDF DownLoad Join now for total 90,000,000 free articles

Article abstract of DOI:10.1016/S0040-4039(00)94494-0

Alkali metal hydride promoted addition of allylic alcohols to aryl vinyl sulfoxides at room temperature gives 2-allyloxyethyl aryl sulfoxides, which, on heating, are converted into γ,δ-unsaturated aldehydes via allylic vinyl ethers.

Full text of DOI:10.1016/S0040-4039(00)94494-0

Products guided by the article

Product name:1-Chloro-4-[2-((E)-3,7-dimethyl-octa-2,6-dienyloxy)-ethanesulfinyl]-benzene

Cas No:130655-08-2

R&D Labs maybe for 130655-08-2

Beijing Mediking Biopharm Co., Ltd.

Contact:+86-10-89753524/81760121/81769521

Address:Hongxianghong Incubator, Beiqijia Town, Changping district, Beijing, China
Yancheng Smiling Imp & Exp Co., Ltd.

Contact:+86-515-83173586

Address:Rm1207, BLD#03, Phoenix Plaza, Juheng Road, Yancheng, Jiangsu, P.R. China
PINGYUAN SIHUAN PHARMACEUTICAL CO., LTD

Contact:+86-531-55696072

Address:#2766,yinxiu Road, Economic Development Zone, Pingyuan Country, Shandong Province, China.
Feis International Trade Co,. Ltd

Contact:13961823444-18235944442

Address:Wuxi jiangsu
Shandong Xiangde Biotechnology Co., Ltd

Contact:+86 -15066639877

Address:Sanba street

Relevant to this article

Synthesis of chiral difluorinated [6]-gingerol

Doi:10.1016/0040-4020(95)00868-9
(1996)
Doi:10.1002/zaac.19673530311
(1967)
Stereoselective hydride reductions of cyclic N-diphenylphosphinyl imines. Highly diastereoselective syntheses of protected primary amines

Doi:10.1021/jo00128a009
(1995)
The first synthesis of N-alkyl-N-arylthiocarbamoylacetates and acetic acids

Doi:10.1080/00397910008087354
(2000)
Design, synthesis, and biological activity of a potent inhibitor of the neuropeptidase N-acetylated alpha-linked acidic dipeptidase.

Doi:10.1021/jm950801q
(1996)
Concise synthesis of pentenyl phenyl acrylic acid

Doi:10.1080/00397910701473333
(2007)

Article Doi