Preparation and rearrangement of 2-allyloxyethyl aryl sulfoxides; a mercury-free claisen sequence

DOI: 10.1016/S0040-4039(00)94494-0

Source and publish data:

Tetrahedron Letters p. 4041 - 4044 (1990)

Update date:2022-09-26

Topics:

Authors:

Mandai, Tadakatsu

Ueda, Masaki

Hasegawa, Shun-Ichi

Kawada, Mikio

Tsuji, Jiro

Saito, Seiki

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Article abstract of DOI:10.1016/S0040-4039(00)94494-0

Alkali metal hydride promoted addition of allylic alcohols to aryl vinyl sulfoxides at room temperature gives 2-allyloxyethyl aryl sulfoxides, which, on heating, are converted into γ,δ-unsaturated aldehydes via allylic vinyl ethers.

Full text of DOI:10.1016/S0040-4039(00)94494-0

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