Angewandte Chemie - International Edition p. 10316 - 10320 (2020)
Update date:2022-09-26
Topics:
Gevorgyan, Vladimir
Kvasovs, Nikita
Ratushnyy, Maxim
Sarkar, Sumon
A mild visible-light-induced Pd-catalyzed intramolecular C?H arylation of amides is reported. The method operates by cleavage of a C(sp2)?O bond, leading to hybrid aryl Pd-radical intermediates. The following 1,5-hydrogen atom translocation, intramolecular cyclization, and rearomatization steps lead to valuable oxindole and isoindoline-1-one motifs. Notably, this method provides access to products with readily enolizable functional groups that are incompatible with traditional Pd-catalyzed conditions.
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Doi:10.1021/jm100087s
(2010)Doi:10.1016/0040-4020(95)00868-9
(1996)Doi:10.1002/zaac.19673530311
(1967)Doi:10.1021/jo00128a009
(1995)Doi:10.1080/00397910008087354
(2000)Doi:10.1021/jm950801q
(1996)
