Journal of Organic Chemistry p. 6236 - 6240 (1990)
Update date:2022-08-02
Topics:
Chen, Cheng-yi
Hart, David J.
Intramolecular Diels-Alder cycloadduct 10 was converted to the Stemona alkaloid stenine (1) via a reaction sequence that features a Curtius rearrangement (12 -> 13), Eschenmoser-Claisen rearrangement (19 -> 20) and stereoselective free radical allylation
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(2011)
