Journal of Organometallic Chemistry p. 173 - 185 (1990)
Update date:2022-08-17
Topics:
Dubuffet, Thierry
Bidon, Corinne
Sauvetre, Raymond
Normant, Jean-F.
Epoxidation of fluoroallylic alcohols with VO(acac)2 or Ti(OiPr)4 + TBHP results in high diastereoselectivity (90-95percent).Epoxidation with m-CPBA gives the erythro isomer as the major component, as opposed to the hydrocarbon series.The ring opening of epoxy alcohols by nucleophiles is easy.
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