Epoxydation diastereoselective d'alcools allyliques monofluores

DOI: 10.1016/0022-328X(90)80196-7

Source and publish data:

Journal of Organometallic Chemistry p. 173 - 185 (1990)

Update date:2022-08-17

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Authors:

Dubuffet, Thierry

Bidon, Corinne

Sauvetre, Raymond

Normant, Jean-F.

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Article abstract of DOI:10.1016/0022-328X(90)80196-7

Epoxidation of fluoroallylic alcohols with VO(acac)2 or Ti(OiPr)4 + TBHP results in high diastereoselectivity (90-95percent).Epoxidation with m-CPBA gives the erythro isomer as the major component, as opposed to the hydrocarbon series.The ring opening of epoxy alcohols by nucleophiles is easy.

Full text of DOI:10.1016/0022-328X(90)80196-7

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