Asymmetric allylic alkylation catalyzed by palladium complexes with atropisomeric quinazolinone phosphine ligands

Article abstract of DOI:10.1016/S0040-4039(98)02599-4

Asymmetric inductions up to 52% ee and 87% ee have been achieved with palladium catalyzed allylic alkylation reactions using a new class of atropisomeric monodentate ((R)-1b) and chelate (2) quinazolinone phosphine ligands, respectively.