Journal of the Chemical Society, Faraday Transactions 1: Physical Chemistry in Condensed Phases p. 3501 - 3510 (1988)
Update date:2022-08-17
Topics:
Tomellini, Massimo
Cation-deficient nickel oxides have been investigated by X-ray photoelectron spectroscopy.The high-binding-energy features in the O(1s), Ni(2p) X.p.s. of defective NiO are described as multielectron final states, induced by defective sites.These sites are described as (NiO6)9- molecular clusters because of the d hole.The energy shift between the main peak and the satellite, in both the O(1s) and Ni(2p) X.p.s spectra, is due to a change in the ionic charge and in the oxygen coordination induced by cation vacancies.
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