Tetrahedron Letters p. 4187 - 4190 (1984)
Update date:2022-08-11
Topics:
McMurry, John E.
Kocovsky, Pavel
Olefins are converted into allylic acetates by treatment in acetic acid with a catalytic amount of palladium bis(trifluoroacetate) and one equivalent of benzoquinone as oxidant.The reaction is selective for oxidation of a terminal methyl group of geranylacetone.
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