
Journal of the Electrochemical Society p. 736 - 739 (1989)
Update date:2022-08-16
Topics:
Forbes
Zukotynski
One micron silicon dioxide films are found to be rapidly reduced by aluminum at temperatures above 450°C. The resulting Al2O3 is found to be in discrete planar regions within the SiO2. The redction process will lead to the formation of a defect-filled insulator whch will be breached by conductive paths. The process is strongly field-assisted with a zero field activation energy of 2.3 ev. It is suggested that the rate of reaction is determined by the rate of migration of ionic silicon, a product of the reducing reaction, in porous Al2O3.
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