Journal of Organic Chemistry p. 705 - 706 (1994)
Update date:2022-08-11
Topics:
Sarko, Christopher R.
Guch, Ian C.
DiMare, Marcello
A new chelation-controlled, α-chiral ketone reduction protocol is presented based on titanium tetrachloride and a wide variety of reducing agents.Features of the proposed intermediate titanium chelates necessary to obtain high diastereoselectivity are dis
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