Asymmetric Synthesis of allo-Threonine and Threonine; the Use of a Chiral Pyridoxal-like Pyridinophane-Zinc Complex as an Enzyme Mimic

DOI: 10.1039/C39870000095

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Journal of the Chemical Society. Chemical communications p. 95 - 96 (1987)

Update date:2022-08-11

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Authors:

Kazuhara, Hiroyoshi

Watanabe, Naoyuki

Ando, Makoto

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Article abstract of DOI:10.1039/C39870000095

allo-Threonine and threonine having 88 and 74percent enantiomeric excess (e.e.), respectively, were obtained in 1.7:1 ratio, by a biomimetic aldol condensation between acetaldehyde and the zinc chelate of a Schiff base produced from glycine and a chiral, pyridoxal-like pyridinophane derivative (2).

Full text of DOI:10.1039/C39870000095

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