Journal of the Chemical Society. Perkin transactions I p. 501 - 507 (1991)
Update date:2022-08-30
Topics:
Davies, Stephen G.
Shipton, Mark R.
The synthesis of tricarbonyl(η6-pyridine)chromium(0) complexes is accomplished via complexation of 2-silylpyridines with subsequent fluoride ion-mediated desilylation under mild conditions.The tricarbonylchromium(0) complexes of pyridine, 2-methylpyridine, 3-methylpyridine, 2-ethylpyridine, 2-(but-3-enyl)pyridine and 2-(6-trimethylsilylpyridyl)-1,3-dioxolane are prepared.Deprotonation (lithium diisopropylamide) and methylation (methyl iodide) of tricarbonyl(η6-pyridine)chromium(0) converts it cleanly to tricarbonyl(η6-2-methylpyridine)chromium(0).
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