Synthesis and Reactivity Towards Dioxygen of Some Manganese(II) Complexes of Tertiary Amines. Crystal Structures of >, 2> and

DOI: 10.1039/DT9950000701

Source and publish data:

Journal of the Chemical Society, Dalton Transactions p. 701 - 706 (1995)

Update date:2022-08-11

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Authors:

Lane, Helen P.

Godfrey, Stephen M.

Pritchard, Robin G.

McAuliffe, Charles A.

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Article abstract of DOI:10.1039/DT9950000701

Some manganese(II)-tertiary amine complexes of stoichiometry MnX2(NR3) have been prepared for the first time.Magnetic susceptibility and X-ray crystallographic studies on (R=Et or n-Pr) indicate that the complexes have a dimeric structure, in contrast to the analogous tertiary phosphine complexes which are polymeric.The crystal structure of which contains a mononuclear manganese site has also been determined.This complex is postulated to arise from reaction of a solution of with trace quantities of moisture.The reaction of the complexes with dioxygen has also been examined: shows no interaction, absorbs 2 mol of dioxygen per mol of complex, whereas absorbs anly 1.In contrast to the analogous tertiary phosphine complexes, the complexes do not exhibit reversible binding of dioxygen.

Full text of DOI:10.1039/DT9950000701

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