Journal of Molecular Structure p. 39 - 48 (1992)
Update date:2022-08-10
Topics:
Konings, R. J. M.
Booij, A. S.
The infrared spectra of the vapours above chromium, iron and nickel diiodide have been studied by high-temperature infrared spectroscopy.The gaseous molecules CrI2, FeI2 and NiI2 were all identified and the interpretation of the spectra is in agreement with a linear structure.Additional strong absorption bands in the spectra of the vapour phase above liquid CrO2 and FeI2 were assigned to dimeric (MI2)2 molecules.Valence force constants and thermodynamic quantities have been calculated.
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