Facile aerobic photo-oxidative synthesis of α-diketones from alkynes

DOI: 10.1016/j.tetlet.2010.12.029

Source and publish data:

Tetrahedron Letters p. 875 - 877 (2011)

Update date:2022-08-26

Topics:

Authors:

Nobuta, Tomoya

Tada, Norihiro

Hattori, Kasumi

Hirashima, Shin-Ichi

Miura, Tsuyoshi

Itoh, Akichika

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Article abstract of DOI:10.1016/j.tetlet.2010.12.029

We report a useful method for facile aerobic photo-oxidative synthesis of α-diketones from alkynes with MgBr₂·OEt₂. This procedure provides a practical synthetic method of α-diketones using easily handled bromine sources, harmless visible light, and molecular oxygen as terminal oxidant.

Full text of DOI:10.1016/j.tetlet.2010.12.029

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