Synthesis and Structure of the New Cubane-like Cluster PF6, containing only Terminal Phosphine Ligands

DOI: 10.1039/c39920000910

Source and publish data:

Journal of the Chemical Society. Chemical communications p. 910 - 911 (1992)

Update date:2022-08-28

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Authors:

Cecconi, Franco

Ghilardi, Carlo A.

Midollini, Stefano

Orlandini, Annabella

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Article abstract of DOI:10.1039/c39920000910

The cubane-like PF6 and the stellated octahedron PF6 clusters have been obtained by reaction of Fe(ClO4)2 with PEt3 and H2X (X=Te, Se), in the presence of PF6^-; a crystal structure of the tellurium derivative has been determined.

Full text of DOI:10.1039/c39920000910

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