Chemistry Letters p. 1207 - 1210 (1994)
Update date:2022-08-04
Topics:
Nagashima, Hideo
Kato, Yoshiyuki
Yamaguchi, Hirofumi
Kimura, Eiji
Kawanishi, Teruhiko
et al.
The organoplatinum compound of C60, C60Ptn (n=1-2), was prepared either by the reaction of C60 with Pt(dba)2 or by the thermal disproportionation of C60Ptn (n=ca. 1).The C60Ptn obtained catalyzed the hydrogenation of diphenylacetylene regardless of the platinum content.Cleavage of carbon-platinum bonds of C60Ptn (n=ca. 1) was accomplished by the reactions with phosphines or phosphites, which provided general access to (η2-C60)PtL2
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