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Studies on . Part 2. Kinetic and Mechanistic Studies on the Reaction of trans,mer- with 2,2'-Bipyridine or Et2PCH2CH2PEt2 at 25 deg C

DOI: 10.1039/DT9910001761

Source and publish data:

Journal of the Chemical Society, Dalton Transactions p. 1761 - 1764 (1991)

Update date:2022-08-10

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Authors:

Henderson, Richard A.Henderson, Richard A.

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Article abstract of DOI:10.1039/DT9910001761

The kinetics of the reactions between trans,mer- and L-L = 2,2'-bipyridine or Et2PCH2CH2PEt2 to give mer- have been studied in tetrahydrofuran (thf) at 25 deg C.Previous proposals that in solution the reactant is the solvento-species have been substantiated by kinetic studies which demonstrate that chloride must bind to the reactant prior to interaction with the substrates.The kinetics has been interpreted in terms of a series of associative-interchange steps.Strong evidence for the associative mechanism comes from the observation that the solvento-species does not react with L-L, a pattern which is inconsistent with a dissociative mechanism.

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Product name:mer-{1,2-bis(diethylphosphino)ethane}trichloro(dimethylphenylphosphine oxide-κO)vanadium(III)

Cas No:136244-48-9

136244-48-9

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