Carboalumination/Transmetalation/Conjugate Addition: A New Catalytic Cu(I)-Induced Process for the 1,4-Delivery of Vinylic Groups to Enones

DOI: 10.1021/jo00020a012

Source and publish data:

Journal of Organic Chemistry p. 5761 - 5763 (1991)

Update date:2022-08-16

Topics:

Authors:

Lipshutz, Bruce H.

Dimock, Stuart H.

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Article abstract of DOI:10.1021/jo00020a012

Exposure of vinylalanes, derived from carbometalations of 1-alkynes, to catalytic amounts of CuCN*2LiCl in the presence of an α,β-unsaturated carbonyl group affords products of vinylic ligand transfer in a 1,4-manner

Full text of DOI:10.1021/jo00020a012

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