Asymmetric Synthesis in the Nickel-complex-catalysed Formation of Olefins from Allyl Alcohols and Grignard Reagents

DOI: 10.1039/c39810000681

Source and publish data:

Journal of the Chemical Society. Chemical communications p. 681 - 682 (1981)

Update date:2022-08-22

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Authors:

Cherest, Marc

Felkin, Hugh

Umpleby, J. David

Davies, Stephen G.

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Article abstract of DOI:10.1039/c39810000681

The reaction of three isomeric pentenols with methyl magnesium bromide catalysed by (-)DIOP nickel dichloride leads to optically active 3-methylpent-1-ene, with the optical yield and product configuration related to the configuration of the initially formed (η³-allyl)nickel intermediates.

Full text of DOI:10.1039/c39810000681

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