Asymmetric Synthesis in the Nickel-complex-catalysed Formation of Olefins from Allyl Alcohols and Grignard Reagents

DOI: 10.1039/c39810000681

Source and publish data:

Journal of the Chemical Society. Chemical communications p. 681 - 682 (1981)

Update date:2022-08-22

Topics:

Authors:

Cherest, Marc

Felkin, Hugh

Umpleby, J. David

Davies, Stephen G.

Read Full Text PDF DownLoad Join now for total 90,000,000 free articles

Article abstract of DOI:10.1039/c39810000681

The reaction of three isomeric pentenols with methyl magnesium bromide catalysed by (-)DIOP nickel dichloride leads to optically active 3-methylpent-1-ene, with the optical yield and product configuration related to the configuration of the initially formed (η³-allyl)nickel intermediates.

Full text of DOI:10.1039/c39810000681

View Article Online / Journal Homepage / Table of Contents for this issue

View Article Online

Products guided by the article

Product name:3-Methyl-1-pentene

Cas No:13643-02-2

R&D Labs maybe for 13643-02-2

enantiotech corporation ltd

Contact:+86-0760-85282375

Address:zhongjing road,zhongshan torch hi-tech industrial development zone
Rugao Jinling Chemical Co., Ltd.(expird)

Contact:0086-513-68005586

Address:Lianluo new village huangshi town Rugao city Jiangsu Province.
Hangzhou J&H Chemical Co., Ltd.

website:http://www.jhechem.com/

Contact:+86-571-87396432

Address:No.200 Zhenhua Rd.Xihu Industrial Park, Hangzhou 310030, China
Aminodiscovery Co.,Ltd.

Contact:+86-535-8888888

Address:No.161 Haishi Rd.
Dalian Synco Chemical Co., Ltd.

Contact:+86-411-83635150

Address:Rm 1004, 24, Tangshan Street, Dalian

Relevant to this article

A Practical Synthesis of 2,6-Dicarboxyfluorenone

Doi:10.1039/a805065a
(1998)
Doi:10.1021/ja01030a014
(1969)
Poised on the brink between a bistable complex and a compound

Doi:10.1021/ol0171362
(2002)
Doi:10.1039/jr9630002723
(1963)
Doi:10.1016/S0022-4596(05)80239-7
(1992)
Highly fluorescent blue-green emitting phenanthroimidazole derivatives: Detail experimental and DFT study of structural and donating group effects on fluorescence properties

Doi:10.1016/j.dyepig.2018.06.020
(2018)

Article Doi