Inorganic Chemistry p. 2252 - 2257 (1977)
Update date:2022-08-29
Topics:
Wilson
Naulin
Bougon
A new U(V) compound, UF2(SO3F)3, has been synthesized by the reaction of UF6 and SO3 in both the gaseous phase and CFCl3 solution. This leads to a blue-green solid, the x-ray powder diffraction pattern of which has been recorded. Its oxidation state has been deduced from chemical analysis, the electronic absorption spectrum, and magnetic measurements. The environment around uranium is discussed from Raman and infrared spectra recorded at ambient and liquid nitrogen temperatures.
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Doi:10.1002/ejoc.201701652
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(1989)Doi:10.1021/jacs.9b02486
(2019)Doi:10.1016/j.jphotochem.2016.09.022
(2017)Doi:10.1039/jr9610002423
(1961)
