
Journal of Organic Chemistry p. 5556 - 5559 (1995)
Update date:2022-08-11
Topics:
Marshall, James A.
Perkins, Jolyon F.
Wolf, Mark A.
The stannanes (S)-1a, (R)-1b, and (S)-1c add to (S)- and (R)-2-methyl-3-(benzyloxy)propanal ((S)-2 and (R)-2) to afford the syn,syn (BF3*OEt2 promotion), syn,anti (MgBr2*OEt2 promotion), anti,anti (SnCl4-derived reagent in CH2Cl2), and anti,syn (SnCl4-derived reagent in hexane) stereotriad adducts 3, 4, 6, and 7.
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(1995)