AZATRICYCLES FROM SUBSTITUTED PYRIDINES. SYNTHESIS AND REARRANGEMENT OF N-ETHOXYCARBONYL-2-AZATRICYCLO3,7>DEC-8-ENES

DOI: 10.1016/S0040-4020(01)82393-0

Source and publish data:

Tetrahedron p. 8499 - 8514 (1991)

Update date:2022-08-05

Topics:

Authors:

Krow, Grant R.

Lee, Yoon B.

Raghavachari, Ramesh

Szczepanski, Steven W.

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Article abstract of DOI:10.1016/S0040-4020(01)82393-0

The scope and relative rates of intramolecular cycloaddition reactions of methyl-substituted 2-(3-butenyl)-1,2-dihydropyridines 4 have been studied.Cycloadducts 5 can be rearranged to 14 upon reaction with bromine, except when olefinic methyl groups are present.

Full text of DOI:10.1016/S0040-4020(01)82393-0

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Product name:N-Ethoxycarbonyl-8-phenyl-2-azatricyclo<4.3.1.0^3,7>dec-8-ene

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