A new, highly selective, water-soluble rhodium catalyst for methyl acrylate hydroformylation

DOI: 10.1016/0022-328X(95)05595-1

Source and publish data:

Journal of Organometallic Chemistry p. 11 - 16 (1995)

Update date:2022-08-29

Topics:

Authors:

Fremy, Georges

Castanet, Yves

Grzybek, Ryszard

Minflier, Eric

Mortreux, Andre

et al. et al.

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Article abstract of DOI:10.1016/0022-328X(95)05595-1

Hydroformylation of methylacrylate to α-aldehyde can be achieved in a two-phase system in the presence of two new water-soluble phosphines.High yields and selectivities of α-aldehyde (ca. 80percent with a α/β ratio of 1:20) were obtained.Spectroscopic studies have been carried out and some new rhodium complexes formed in situ in catalytic systems have been identified.Keywords: Hydroformylation; Methyl acrylate; Water-soluble phosphines; Rhodium; Catalysis; Two phase system

Full text of DOI:10.1016/0022-328X(95)05595-1

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