13C magnetic resonance studies. 144.1 An examination of β-enolization in the bicyclo[3.3.1]-and [3.2.2]nonan-2-one system

DOI: 10.1139/v93-146

Source and publish data:

Canadian Journal of Chemistry p. 1099 - 1105 (1993)

Update date:2022-08-16

Topics:

Authors:

Muir, David J.

Stothers

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Article abstract of DOI:10.1139/v93-146

While 3, 3-dimethylbicyclo[3.3. l]nonan-2-one (5) is stable under strongly basic conditions (/-BuCT//-BuOH/185°C), its isomer, 3, 3-dimethylbicyclo[3. 2.2]nonan-2-one (6), is slowly transformed to 5. Similarly, 3, 3-dimethylbicyclo-[3.2.2]non-6-en-2-one (

Full text of DOI:10.1139/v93-146

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