Berichte der Bunsengesellschaft/Physical Chemistry Chemical Physics p. 688 - 694 (1987)
Update date:2022-08-11
Topics:
Schottler
Homann
H and O atoms and methyl radicals produced in microwave discharges of H//2/He, O//2/He and CH//4/He mixtures, respectively, were scavenged by supersonic nozzle probing with subsequent freezing and reaction with dimethyl disulfide on a liquid nitrogen cooled wall. The main reaction products for the three kinds of radicals were CH//3SH, CH//3S(O)SCH//3 and CH//3SCH//3, respectively. The scavenging efficiencies for the different radicals were determined and measured as a function of the gas phase radical concentration, the flow of scavenger molecules, the pressure in the vacuum chamber, and the conditions of the discharge and the flow through the sampling nozzle. It is concluded that this method is suitable for light radicals with reservations in the case of H atoms and can probably be used with still better success for heavier radicals.
View MoreZhongshan Haihong Medicine Co., Ltd.
Contact:86-0760-86925778 (0)18824993998
Address:A7 building,lianyuan road Torch Hi-tech Industrial Development Zone
Nanjing distinctions Medical Technology Co., Ltd.(expird)
Contact:+86-15996203785 13914714059
Address:nanjing,jiangsu , China
Contact:86 21 3772 9386
Address:Rm.1803,Starry Bldg.1,1505 Meijiabang Road,Shanghai 201620 China
Contact:+86-29-88710656
Address:South Tai bai Road, High Tech Development Zone, Xi'an China
Zhangjiagang Golden Reach Fine Chemical Co.,LTD.
Contact:+86-512-6585 6968
Address:Changfu Road, Dongsha Chemical Industry Park, Zhangjiagang City, Jiangsu Province, China
Doi:10.1081/SCC-100105130
(2001)Doi:10.1021/ja029964b
(2003)Doi:10.1021/ma0359638
(2004)Doi:10.1021/ja00295a032
(1985)Doi:10.1021/ic502315m
(2015)Doi:10.1016/0009-3084(72)90007-2
(1972)