Recueil des Travaux Chimiques des Pays-Bas p. 56 - 58 (1992)
Update date:2022-08-15
Topics:
Sjouken, Ronald
Ebens, Rijko
Kellogg, Richard M.
Condensation of R-(+)-1-(2-chlorophenyl)-2,2-dimethyl-propan-1,3-diol (2) with a derivative (1) of 1-formylcyclohexene substituted in the 3-position with an acetoxy group proceeded with absolute stereospecificity at the acetal center.Catalytic alkylation of the ?-allyl complex obtained upon reaction with Pd with the anion of dimethylmalonate proceeded at the 3-position of the cyclohexyl ring with complete stereocontrol.
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