Page 11 of 12
Journal of the American Chemical Society
1
2
3
4
5
6
7
8
9
(47)
Peterson, T. H.; Golden, J. T.; Bergman, R. G. Deprotonation of the Transition Metal
Hydride (η5-C5Me5)(PMe3)IrH2. Synthesis and Chemistry of the Strongly Basic Lithium Iridate (η5-
C5Me5)(PMe3)Ir(H)(Li). Organometallics 1999, 18, 2005.
(48)
Fluoroaromatics by [(η5-C5Me5)RhI(2,2′-bipyridine)]. Organometallics 2014, 33, 4349.
(49) Braun, T.; Noveski, D.; Ahijado, M.; Wehmeier, F. Hydrodefluorination of
Nakai, H.; Jeong, K.; Matsumoto, T.; Ogo, S. Catalytic C–F Bond Hydrogenolysis of
pentafluoropyridine at rhodium using dihydrogen: detection of unusual rhodium hydrido complexes.
10
11
12
13
14
15
16
17
18
19
20
21
22
23
24
25
26
27
28
29
30
31
32
33
34
35
36
37
38
39
40
41
42
43
44
45
46
47
48
49
50
51
52
53
54
55
56
57
58
59
60
Dalton Trans. 2007, 3820.
(50)
dimethyl sulfoxide. Conductometric studies. J. Am. Chem. Soc. 1974, 96, 1782.
(51) Puri, M.; Gatard, S.; Smith, D. A.; Ozerov, O. V. Competition Studies of Oxidative
Addition of Aryl Halides to the (PNP)Rh Fragment. Organometallics 2011, 30, 2472.
(52) Gatard, S.; Guo, C.; Foxman, B. M.; Ozerov, O. V. Thioether, Dinitrogen, and Olefin
Exner, J. H.; Steiner, E. C. Solvation and ion pairing of alkali-metal alkoxides in
Complexes of (PNP)Rh:ꢀ Kinetics and Thermodynamics of Exchange and Oxidative Addition Reactions.
Organometallics 2007, 26, 6066.
(53)
Kameo, H.; Yamamoto, J.; Asada, A.; Nakazawa, H.; Matsuzaka, H.; Bourissou, D.
Palladium–Borane Cooperation: Evidence for an Anionic Pathway and Its Application to Catalytic
Hydro-/Deutero-dechlorination. Angew. Chem. Int. Ed. 2019, 58, 18783.
(54)
Obligacion, J. V.; Bezdek, M. J.; Chirik, P. J. C(sp2)–H Borylation of Fluorinated Arenes
Using an Air-Stable Cobalt Precatalyst: Electronically Enhanced Site Selectivity Enables Synthetic
Opportunities. J. Am. Chem. Soc. 2017, 139, 2825.
(55)
Selmeczy, A. D.; Jones, W. D.; Partridge, M. G.; Perutz, R. N. Selectivity in the
activation of fluorinated aromatic hydrocarbons by rhodium complexes [(C5H5)Rh(PMe3)] and
[(C5Me5)Rh(PMe3)]. Organometallics 1994, 13, 522.
(56)
Vollmer, M. V.; Ye, J.; Linehan, J. C.; Graziano, B. J.; Preston, A.; Wiedner, E. S.; Lu,
C. C. Cobalt-Group 13 Complexes Catalyze CO2 Hydrogenation via a Co(−I)/Co(I) Redox Cycle. ACS
Catal. 2020, 10, 2459.
(57)
M.; Brookhart, M. Dihydrogen Complexes of Iridium and Rhodium. Inorg. Chem. 2012, 51, 4672.
(58) Douglas, T. M.; Brayshaw, S. K.; Dallanegra, R.; Kociok-Köhn, G.; Macgregor, S. A.;
Findlater, M.; Schultz, K. M.; Bernskoetter, W. H.; Cartwright-Sykes, A.; Heinekey, D.
Moxham, G. L.; Weller, A. S.; Wondimagegn, T.; Vadivelu, P. Intramolecular Alkyl Phosphine
Dehydrogenation in Cationic Rhodium Complexes of Tris(cyclopentylphosphine). Chem. Eur. J. 2008,
14, 1004.
(59)
Oldham, W. J.; Hinkle, A. S.; Heinekey, D. M. Synthesis and Characterization of
Hydrotris(pyrazolyl)borate Dihydrogen/Hydride Complexes of Rhodium and Iridium. J. Am. Chem. Soc.
1997, 119, 11028.
(60)
Butler, S. J. Quantitative determination of fluoride in pure water using luminescent
europium complexes. Chem. Commun. 2015, 51, 10879.
(61)
Zhou, J.; Kuntze-Fechner, M. W.; Bertermann, R.; Paul, U. S. D.; Berthel, J. H. J.;
Friedrich, A.; Du, Z.; Marder, T. B.; Radius, U. Preparing (Multi)Fluoroarenes as Building Blocks for
Synthesis: Nickel-Catalyzed Borylation of Polyfluoroarenes via C–F Bond Cleavage. J. Am. Chem. Soc.
2016, 138, 5250.
(62)
Fluorides via C–F Cleavage. J. Am. Chem. Soc. 2015, 137, 12470.
(63) Lindup, R. J.; Marder, T. B.; Perutz, R. N.; Whitwood, A. C. Sequential C–F activation
Liu, X.-W.; Echavarren, J.; Zarate, C.; Martin, R. Ni-Catalyzed Borylation of Aryl
and borylation of fluoropyridines via intermediate Rh(I) fluoropyridyl complexes: a multinuclear NMR
investigation. Chem. Commun. 2007, 3664.
(64)
Kim, K.; Lee, E. Cobalt-Catalyzed C–F Bond Borylation of Aryl Fluorides. Org. Lett. 2018, 20, 7249.
(65) Niwa, T.; Ochiai, H.; Hosoya, T. Copper-Catalyzed ipso-Borylation of Fluoroarenes.
ACS Catal. 2017, 7, 4535.
Lim, S.; Song, D.; Jeon, S.; Kim, Y.; Kim, H.; Lee, S.; Cho, H.; Lee, B. C.; Kim, S. E.;
ACS Paragon Plus Environment