
Journal of Fluorine Chemistry p. 535 - 537 (1984)
Update date:2022-08-11
Topics:
Iwamoto, Hidetoshi
Sonoda, Takaaki
Kobayashi, Hiroshi
Anion-catalyzed phase-transfer catalysis was successfully applied to diazotization of pentafluoroaniline in a dichloromethane-aqueous sulfuric acid two-phase system.The resulting diazonium group was coupled in situ with anisole, 1-methoxynaphthalene, and mesitylene, and replaced in situ with bromo, hydryl, and phenyl substituents under a two-phase condition.
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