Branched-Chain Carbohydrate Lactones from a Samarium(II) Iodide-Promoted Serial Deoxygenation-Carbonyl Addition Reaction

DOI: 10.1021/jo00067a045

Source and publish data:

Journal of Organic Chemistry p. 4061 - 4069 (1993)

Update date:2022-08-05

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Authors:

Enholm, Eric J.

Jiang, Shujun

Abboud, Khalil

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Article abstract of DOI:10.1021/jo00067a045

A new deoxygenation-carbonyl addition reaction mediated by samarium(II) iodide (SmI2) in THF/HMPA was examined with carbohydrate lactones and several substrates containing an α-alkoxy carboxylic ester.In a single reaction, these compounds were deoxygenate

Full text of DOI:10.1021/jo00067a045

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