Synthesis and Reactivity of Dioxycarbenium Ions from Epoxy Esters and Cationic Zirconium Complexes

DOI: 10.1021/jo00074a006

Source and publish data:

Journal of Organic Chemistry p. 5880 - 5882 (1993)

Update date:2022-08-16

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Authors:

Wipf, Peter

Xu, Wenjing

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Article abstract of DOI:10.1021/jo00074a006

Rearrangement of epoxy esters in the presence of Cp2Zr(R)(+) or Cp2Zr(Cl)(+) results in synthetically useful dioxycarbenium intermediates.Acetals, ortho esters, and tetrahydrofurans are prepared by ligand transfer from zirconium, intramolecular trapping,

Full text of DOI:10.1021/jo00074a006

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