Synthesis and Reactivity of Dioxycarbenium Ions from Epoxy Esters and Cationic Zirconium Complexes

DOI: 10.1021/jo00074a006

Source and publish data:

Journal of Organic Chemistry p. 5880 - 5882 (1993)

Update date:2022-08-16

Topics:

Authors:

Wipf, Peter

Xu, Wenjing

Read Full Text PDF DownLoad Join now for total 90,000,000 free articles

Article abstract of DOI:10.1021/jo00074a006

Rearrangement of epoxy esters in the presence of Cp2Zr(R)(+) or Cp2Zr(Cl)(+) results in synthetically useful dioxycarbenium intermediates.Acetals, ortho esters, and tetrahydrofurans are prepared by ligand transfer from zirconium, intramolecular trapping,

Full text of DOI:10.1021/jo00074a006

Products guided by the article

Product name:1,2,3-Propanetriol, 2-methyl-, 1-benzoate

Cas No:139710-65-9

R&D Labs maybe for 139710-65-9

Anhui Xinyuan Technology Co.,Ltd

Contact:0086-559-3515800

Address:No.16 Zijin Rd, Circular Economic Zone, Huizhou District, Huangshan Anhui China
Shangyu Sanhechemicals Co.,LTD.

Contact:86-0571-56696839

Address:Num.2952,Nanhuan Road,Binjiang District,Hangzhou,China
jiangsu haian chemical co.,ltd.

Contact:86-513-15851283853

Address:No.99,Changjiang West Road,Haian County,Jiangsu Province,China
Fujian Huitian Biological Pharmacy Co., Ltd.

Contact:0086-598-8300831; 8339920

Address:No.46,Taijiang Road,Sanming City,Fujian,China
Anhui Asahikasei Chemical Co., Ltd

Contact:86-551-4259770

Address:No. 88 Linquan Road Hefei Anhui China

Relevant to this article

Substituent effect at the C4-position of 1,3a,6a-triazapentalene

Doi:10.1248/cpb.c16-00196
(2016)
Novel series of 17β-pyrazolylandrosta-5,16-diene derivatives and their inhibitory effect on 17α-hydroxylase/C_17,20-lyase

Doi:10.1016/j.steroids.2012.07.001
(2012)
Novel 3-amino-6-chloro-7-(azol-2 or 5-yl)-1,1-dioxo-1,4,2-benzodithiazine derivatives with anticancer activity: Synthesis and QSAR study

Doi:10.3390/molecules201219821
(2015)
A Norbornadiene-Cyclobutadiene Cycloaddition Cascade: Novel Intramolecular ?² + ?² Trapping of a Cyclobutane Ring

Doi:10.1039/c39920000082
(1992)
Synthesis and characterization of an isolable base-stabilized silacycloprop-1-ylidene

Doi:10.1002/anie.201201581
(2012)
Ruthenium-Catalyzed Hydration of Nitriles and Transformation of δ-Keto Nitriles to Ene-Lactams

Doi:10.1021/jo00035a003
(1992)

Article Doi