
Journal of the Chemical Society. Chemical communications p. 1429 - 1431 (1984)
Update date:2022-08-16
Topics:
Viola, Alfred
Locke, John S.
Thermolyses of β-aminoacetylenes with a terminal acetylenic bond and of β-amino-olefins afford retro-ene reactions in which nitrogen acts as the hydrogen donor, whereas alkyl substitution on the terminus of the acetylenic bond leads to a novel, facile cyclization to a 2-alkylidenepyrrolidine.
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