Reactivity of Alkenes at a Diruthenium Centre: Combination with Methylen and Oxidative Activation

DOI: 10.1039/c39890000638

Source and publish data:

Journal of the Chemical Society. Chemical communications p. 638 - 640 (1989)

Update date:2022-08-16

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Authors:

Doherty, Nancy M.

Howard, Judith A. K.

Knox, Selby A. R.

Terrill, Nicholas J.

Yates, Michael I.

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Article abstract of DOI:10.1039/c39890000638

The complex undergoes methylene-ethylene combiation on heating to give propene, and ethylene activation upon oxidation with Ag⁺ to give the μ-vinyl cation ⁺; treatment of the latter with H^- affords , which evolves propene more efficiently on heating.

Full text of DOI:10.1039/c39890000638

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