Synthetic routes to transition-metal-substituted pentadiynylidene complexes

DOI: 10.1002/cber.19971300807

Source and publish data:

Chemische Berichte p. 1063 - 1067 (1997)

Update date:2022-08-29

Topics:

Authors:

Hartbaum, Cornelia

Fischer, Helmut

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Article abstract of DOI:10.1002/cber.19971300807

Sequential reaction of the dimethylamino(ethynyl)carbene complex [(CO)₅W=C(NMe₂)C≡CH] (1) with nBuLi, Cul and BrC≡CSiMes affords the dimethylamino(trimethylsilylbutadiynyl)carbene complex [(CO)₅W=C(NMe₂)CsC-C≡CS

Full text of DOI:10.1002/cber.19971300807

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