Cyclopentadienyl thiocarbonyl complexes of iron: *Fe(CO)2CS>+, Cp*2Fe2(CO)2(CS)2, Cp2Fe2(CO)3(CS), and Cp2Fe2(CO)2(CS)2

Article abstract of DOI:10.1016/0022-328X(90)85140-T

Nucleophiles generally react with the new iron thiocarbonyl complex *Fe(CO)2(CS)>⁺ (Cp^* = η-C5Me5) by attacking at the carbon of the CS ligand.Thus, SMe^- gives the dithioester, Cp^*Fe(CO)2<(C=S)SMe>