SOLVENT EFFECTS ON OPTICAL AND ESR SPECTRA OF ONE-ELECTRON REDUCED SPECIES OF COBALT(III) AND MANGANESE(III) TETRAPHENYLPORPHYRINS PRODUCED BY gamma -RADIOLYSIS AT 77 K.

Article abstract of DOI:10.1246/bcsj.57.1713

One-electron reduction by gamma -ray irradiation of cobalt(III) and manganese(III) tetraphenylporphyrins (ClCo(III)TPP, ClMn(III)TPP, and IMn(III)TPP) in ethanol and MTHF(2-methyltetrahydrofuran) solutions at 77 K results in the reduction of the central m